AASCIT Journal of Chemistry  
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Determination of Heavy Metals in Scrapped Car Paint Dust and Auto Repair Workshop Soil from Southeastern Nigeria: Soil Contamination Assessment
AASCIT Journal of Chemistry
Vol.6 , No. 3, Publication Date: Oct. 28, 2020, Page: 20-28
1219 Views Since October 28, 2020, 518 Downloads Since Oct. 28, 2020
 
 
Authors
 
[1]    

John Kanayochukwu Nduka, Environmental Chemistry and Toxicology Research Unit, Pure and Industrial Chemistry Department, Nnamdi Azikiwe University, Awka, Nigeria.

[2]    

Johnpaul Onyenezi Amuka, Environmental Chemistry and Toxicology Research Unit, Pure and Industrial Chemistry Department, Nnamdi Azikiwe University, Awka, Nigeria.

[3]    

Chioma Perpetua Okafor, Department of Natural Sciences, School of General Studies, Federal Polytechnic, Oko, Nigeria.

 
Abstract
 

Automobiles imported into Nigeria are fairly used and rickety, the net effect is that high automobile waste dot the Nigerian landscape, amidst poverty the vehicles are taken to the workshops for reworking (panel beaten, welding, old paint scrapping, finishing and repainting). Therefore we used integrated pollution index, enrichment factor and geo-accumulation index to establish contamination profiles of used vehicle reworking workshop soil. Scrapped car paint dusts matrix from 55 vehicles and workshop soil were collected from eight (8) car reworking workshops in south eastern Nigerian. They were homogenized, mixed and divided into fine particles that can pass through 0.5mm sieve and digested by standard methods. The filtrates were assayed for cadmium, chromium, lead, manganese, nickel, copper and iron with atomic absorption spectrophotometry (AAS 200A) at their respective wavelength. Result of paint dust shows highest value (mg/kg) Cd (3.36±0.02),Cr (2.95 ±0.01), Pb (4.21±0.03), Mn (3.31±0.01), Ni (3.84±0.02), Cu (7.11±0.01) and Fe (13.25±0.04) for vehicles in workshops D, G, B, A, A, D and H while that of workshop soil were Cd (3.93±0.01), Cr (3.53±0.02), Pb (5.19±0.05), Mn (4.05±0.01), Ni (4.57±0.01), Cu (7.31±0.01) and Fe (16.12±0.08) were reported in workshops F, F, B, A, F, D and G. Contamination assessment [integrated pollution index (IPIn), enrichment factor (EF) and geo-accumulation index (I-geo)] calculated using standard equations were compared with established reference standard showed that workshop soils were anthropogenically polluted with heavy metals from scrapped waste car paint. Reworking used vehicles may contribute to environmental heavy metal burden with its associated public health risks.


Keywords
 

Paint Dust, Soil Heavy Metal Levels, Soil Contamination Assessment, Automobile Waste, Auto-Workshops, Southeastern Nigeria


Reference
 
[01]    

Obiajunwa EI, Pelemo DA, Owolabi SA, Fasai MK, Johnson-Fatokun FO (2002) Characterization of heavy metal pollutants of soils and sediments around a crude-Oil production terminal using EDXRF. Nucl. Instrum. Methods Phys B, 194, 61-64.

[02]    

Adeyi AA, Torto N. (2014). Profiling heavy metal distribution and contamination in soil of old power generation station in Lagos, Nigeria. American Journal of Science and Technology 1 (1): 1-10.

[03]    

Wallace B, Cooper K (1986). The citizens guide to lead: Uncovering a hidden health hazard; NC Press Ltd: Toronto, Canada.

[04]    

Agency for Toxic Substances and Diseases Registry (ATSDRY, 1992) Case studies in environmental medicine-lead toxicity, US Department of Health and Human Services: Washington, DC, USA.

[05]    

Onianwa PC, Adetola IG, Igwegbue CMA, Ojo MF, Tella OO (1999). Trace heavy metal composition of some Nigerian beverages and food drinks. Food Chemistry; 66: 275-279.

[06]    

Bruening K, Kemp FN, Simone N, Holding Y, Louria DB, Bogden JD (1999). Dietary calcium intakes of urban children at risk of lead poisoning. Environ Health Perspect; 107: 431-435.

[07]    

Orisakwe OE, Nduka JK (2009). Lead and cadmium levels of commonly administered pediatric syrups in Nigeria: A public health concern, Science of the Total Environment; 407: 5993-5996.

[08]    

Nduka JK, Orisakwe OE (2009) Heavy metal hazards of pediatric syrup administration in Nigeria: A look at Chromium, Nickel and Manganese. Int. J. Environ. Res. Public Health; 6: 1972 -1.979

[09]    

Fakayode S, Olu-Owolabi I (2003). Trace metal content and estimated daily human intake from chicken eggs in Ibadan. Nigeria. Arch Environ Health; 58 (4): 245-251.

[10]    

Maduabuchi J. MU, Nzegwu CN, Adigba EO, Aloke RU, Ezomike CN, Okocha CE, Obi E, Orisakwe OE (2006) Lead and cadmium exposures from canned and non-canned beverages in Nigeria: A Public Health Concern. Science of the Total Environment.366: 621–626.

[11]    

Obi E, Akunyili D, Ekpo E, Orisakwe O (2006). Heavy metal hazards of Nigerian herbal remedies. Sci Total Environ. 369: 35–41.

[12]    

Nduka JK, Odiba IO, Orisakwe OE, Ukaegbu LD, Sokcibe C (2015). Human health risk assessment of heavy metals in cosmetics in Nigeria, 66 (4): 233-246.

[13]    

Nduka JKC, Orisakwe OE, Maduagwuna CA (2008) Lead levels in paint flakes from buildings in Nigeria: A preliminary study. Toxicology and Industrial Health; 24: 539–542.

[14]    

Nduka JKC, Orisakwe OE, Maduagwu CA (2007) Heavy metals other than lead in flaked paints from buildings in Eastern Nigeria. Toxicology and Industrial Health; 23: 525-528.

[15]    

Orisakwe OE, Asomugha R, Affonne OJ, Obi E, Chilaka KC, Dioka CE (1999) Effect of industrial effluent on soil and water qualities in Nnewi, Nigeria. J. Health. Sci.45: 177-183.

[16]    

Orisakwe OE, Asomugha R, Obi E, Nduka JC, Dioka CE (2004) Impact of effluents from Cable manufacturing plant on food, water and soil qualities in Nnewi, Nigeria. Pakistan. J. Biol. Sci. 8: 744–747.

[17]    

Ketiku AO, Adeyinka O (1999) Leaching of lead from imported and Nigerian earthenware potteryand ceramic household utensils into food and drink. Biol. Appl. Chem.44: 18-20.

[18]    

Kakulu SE (2003). Trace metal concentration in roadside surface soil and tree bark: A measurement of local atmospheric pollution in Abuja, Nigeria. Environmental Monit Assess; 89 (3): 233–242.

[19]    

Nduka JK, Orisakwe OE (2010) Assessment of environmental distribution of lead in some municipalities of South Eastern Nigeria, Int. J. Environ. Res. Public Health; 7: 2501-2513.

[20]    

Schmidt CW (2006) Unfair trade E-waste in Africa. Environ Health Perspect. 144: A232–A235.

[21]    

Orisakwe OE, Frazzoli C (2010). Electronic revolution and electronic wasteland: The west/waste African experience. J. Nat. Env. Sci. 1 (1): 43–47.

[22]    

Frazzoli C, Orisakwe OE, Dragone R, Mantovani A (2010) Diagnostic health risk assessment of electronic waste on the general population in developing countries scenarios. Environmental Impact Assessment Review 30 (6): 388–399.

[23]    

White C, Masanet E, Rosen C, Beckman SJ (2003). Cleaner Prod. 11: 445–458.

[24]    

Emedo C, Jakande T, Aminu U (2001). Comprehensive Practical Agricultural Science for West African Senior Secondary School and Colleges, 1st ed. Hybrid Publishers, Onitsha, Nigeria.

[25]    

Brady NC, Weil RR (1999) The Nature and properties of soils. 12th edition Prentice- Hall, Englewood Cliffs, NJ.

[26]    

Chen,TB, Zheng YM, Mei L, HuangZ C, WuHT, Chen H, Fan K K, Yu Ke, Wu Xio,Tian QZ (2005) Assessment of heavy metals pollution in surface soils of urban parks in Beijing China. Chemosphere 60: 542-551.

[27]    

Wei B, Jiang F, Li X, Mu S (2009) Spatial distribution and contamination assessment of heavy metals in Urban roads dusts from Urunqi, NW China. Michrochemical Journal. Doi: 10.10161/j.micro.2009.06.001.93. 147-152.

[28]    

Liu WH, Zhao JZ, Ouyang ZY, Solderland L, Liu, Liu GH (2005) Impact of Sewage Irrigation on Heavy Metal Distribution and Contamination in Beijing. China Environ. Int. 31, 805-812.

[29]    

Buat-Menard,P and Chesselet, R.(1979) Variable influence of atmospheric flux on the trace metal chemistry of oceanic suspended matter. Earth and Planet. Sci. Lett. 42 (3): 399-411.

[30]    

Quevauviller P, Lavigne R, Cortez L (1989) Impact of Industrial and mine drainage wastes on the heavy metal distribution in the drainage basin and estuary of the Sado River (Portugal). Environ. Pollut. 59: 267-286.

[31]    

Schiff KC, Weisberg SB (1999) Iron as a reference element for determining trace metal enrichment in Southern California coastal shelf sediments Mar Environ Res. 48: 161-176.

[32]    

Sutherland RA (2000) Bed sediment-associated trace metals in an urban stream. Oalu, Hawaii. Environ Geol. 39: 611-627.

[33]    

Turekian KK, Wedepohl, KH (1961) Distribution of the elements in some major units of the earth’s crust. Geol. Soc. Am. Bull.72: 175-192.

[34]    

Muller G (1969) Index of geo-accumulation in sediments of the Rhine River Geojournal 2: 108-118.

[35]    

Ji, YQ, Feng YC, Wu JH, Zhu T, Bai ZP, Duan CQ (2008) Using geo-accumulation index to study to study source profiles of soil dust in China Journal of Environmental Sciences, 20: 571-578.

[36]    

De-Miguel E, Llamas JF, Chacon E, Berg T, Larssen S, Royset O, Vadset M, (1997) Origin and patterns of distribution of trace elements in street dust: unleaded petrol and urban lead, Atmospheric Environment, 31, 2733-2740.

[37]    

Sezgin N, Ozcan HK, Demir G, Nemiloglu S, Bayat C (2003) Determination of heavy metal concentration in street dusts in Istanbul E-5 highway, Environment International 29, 979-985.

[38]    

Gibson MG, Farmer JG (1986) Multi-step chemical extraction of heavy metals from urban soils, Environ. Pollut. B 11, 117-135.

[39]    

Burgos P, Madejon M, Perez-de-Mora A, Cabrera F (2008) Horizontal and vertical variability of soil properties in a trace element contaminated area, International Journal of Applied Earth Observation & Geoinformation, 10: 11-25.

[40]    

Li J, Lu Y, Yin W, Gan H, Zhang C, Deng X, Lian J (2008) Distribution of heavy metals in agricultural soils near a petrochemical complex in Guangzhou, China, Environ. Monit. Assess. Doi: 10.1007/s10661-008-036-x

[41]    

Feng H, Han X, Zhang W, Yu L (2004) A preliminary study of heavy metal contamination in Yangtze River intertidal zone due to urbanization. Mar. Pollut. Bull. 49, 910-915.

[42]    

Bilos C, Colombo JC, Skorupka CN, Rodriguez –Presa MJ (2001). Source, distribution and variability of airborne trace metals in La Plata city area, Argentina. Environ. Pollut.111, 149-158.

[43]    

Kisku GC, Barman SC, Bhrgava SK (2000) Contamination of soils and plants with potentially toxic elements irrigated with mixed industrial effluent and its impact on the environment. Water, Air & Soil Pollution, 120: 121-13.

[44]    

Li Y, Wang YB, Gou X, Su YB, Wang G (2006) Risk assessment of heavy metals in soils and vegetables around non-ferrous metals mining and smelting sites, Baiyin, China, Journal of Environmental Sciences. 18: 1124-1134.

[45]    

Ahmed E, Ishiga H (2006) Trace metal concentrations in street dusts of Dhaka city, Bangladesh, Atmospheric Environment, 40: 3835-3844.

[46]    

Nriagu JO (1988). A silent epidemic of environmental metal poisoning. Environ. Pollut. 50, 139-161.

[47]    

Lu X, Wang L, Li LY, Lei K, Huang L, Kang D (2010) Multivariate statistical analysis of heavy metals in street dust of Baoji NW China J. Hazard. Mater 173, 744-749.

[48]    

Al Ramalli SW, Harrington CF, Ayub M, Haris PI (2005). A botanical based approach for arsenic removal from water. J Environ. Monit. 7, 279-282.

[49]    

Duker A A, Carranza EJM, Hale M (2005). Arsenic geochemistry and health. Environ. Int.31, 631- 641.

[50]    

Unachkwu CN, Agomuo DD, Alasia DD (2008) Pattern of non-communicable diseases among medical admissions in Port-Harcourt, Nigeria. Nigerian Journal of Clinical Practice.

[51]    

Nduka JKC, Orisakwe OE, Ezenweke LO, Chendo MN, Ezenwa TE (2008) Heavy metal contamination of foods by refuse dump sites in Awka, Southeastern Nigeria. TheScientificWorldJOURNAL. DOI 10.1100/tsw 2008.129. 8, 941-948.

[52]    

Dang Z, Liu C, Haigh MJ (2002). Mobility of heavy metals associated with the natural weathering of coal mine soils. Environ. Pollut. 118, 419-426.





 
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