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Vol.6 , No. 1, Publication Date: Apr. 16, 2019, Page: 1-11
 applied for the synthesis of environmental pollutants such as (Glyphosate and Nominee) herbicides. In this study different monomer ratios of Methacrylic acid (MAA) with Styrene (ST) as two function monomers were copolymerized with mixture of; Ethylene Glycol Dimethacrylate (EGDMA) as cross-linker, methanol or chloroform as solvent, and two different types of herbicides as template this mixture initiated by gamma radiation effect at optimum dose 40 KGY. Characterization was performed by Scanning Electron Microscope (SEM), Fourier Transfer Infrared (FTIR), X-Rays Diffraction (XRD), Thermogravimetric analysis (TGA) and Ultraviolet (UV) to study the effect of different parameter in acidic & basic medium at 30°C and thermal study from 30°C-80°C. It give good releasing at 90 /10 MAA/ST in two different types of herbicides after 24 h. From these results, it showed that from 90 to 99% approximately of herbicides can release from Molecular Imprinting Copolymer (MIC).&picture=http://www.aascit.org/aascit/decorators/img/journal/905.jpg)
| [1] | Sabrnal Hanafy El-Hamouly, Department Polymer Chemistry, Faculty of Science, Minofia University, Egypt. |
| [2] | Nabila Ahmed Maziad, Department Polymer Chemistry, National Centre for Radiation Research and Technology, Egyptian Atomic Energy Authority, Nasr City, Cairo, Egypt. |
| [3] | Shimaa Mohamed Khalil, Department Polymer Chemistry, Faculty of Science, Minofia University, Egypt. |
This research mainly purposes the reducing amount of herbicides used in agriculture, protect human from water carried herbicides which one of the main pollutants that cause serious problems by Molecular Imprinting Technology (MIT) applied for the synthesis of environmental pollutants such as (Glyphosate and Nominee) herbicides. In this study different monomer ratios of Methacrylic acid (MAA) with Styrene (ST) as two function monomers were copolymerized with mixture of; Ethylene Glycol Dimethacrylate (EGDMA) as cross-linker, methanol or chloroform as solvent, and two different types of herbicides as template this mixture initiated by gamma radiation effect at optimum dose 40 KGY. Characterization was performed by Scanning Electron Microscope (SEM), Fourier Transfer Infrared (FTIR), X-Rays Diffraction (XRD), Thermogravimetric analysis (TGA) and Ultraviolet (UV) to study the effect of different parameter in acidic & basic medium at 30°C and thermal study from 30°C-80°C. It give good releasing at 90 /10 MAA/ST in two different types of herbicides after 24 h. From these results, it showed that from 90 to 99% approximately of herbicides can release from Molecular Imprinting Copolymer (MIC).
Keywords
Molecular Imprinting Copolymer; Methacrylic Acid; Styrene; Glyphosate; Nominee
Reference
| [01] | I. A, Nicholls; B, r, C. Karlsson; G, D, Olsson; A, M, Rosengren. (2013). Computational Strategies for the Design and Study of Molecularly Imprinted Materials. Ind. Eng. Chem. Res., 52, 13900-13909. |
| [02] | H, Qiu; L, Fan; X, Li; L, Li; M. Sun; C, Luo. (2013). Molecular imprinting polymer for analytical chemistry and application. J. Pharm. Biomed. Anal, 75, 123-129. |
| [03] | Z, Xu; K, M; A, Uddin; T, Kamra; J, Schnadt; L, Ye. (2014). Fluorescent Boronic Acid Polymer Grafted on Silica Particles for Affinity Separation of Saccharides. ACS Appl. Mater. Interfaces, 6, 1406-1414. |
| [04] | Y, Han; X, Yuan; M, Zhu; S, Li; M, J, Whitcombe; S, A, Piletsky. (2014). A Catalytic and Shape-Memory Polymer Reactor. Adv. Funct. Mater. 24, 4996-5001. |
| [05] | Elaheh Mansouri; Mahboobe Sarabi Jamab; Behrouz Ghorani; Seyed Ahmad Mohajeri. (2019). Application of Molecularly Imprinted Film for Extraction of Herbicide Mecoprop from Aqueous Sample. Journal of Applied Research of Chemical -Polymer Engineering. 2 (3), 77-89. |
| [06] | ShanshanWang; YongxinShe; SihuiHong; XinweiDu; MengmengYan; YanliWang; YanQi MiaoWang; WenyanJiang; JingWang. (2019). Dual-template imprinted polymers for class-selective solid-phase extraction of seventeen triazine herbicides and metabolites in agro-products. Journal of Hazardous Materials. 367, 686-693. |
| [07] | G, Vasapollo; R, D; Sole, L; Margola, M; R, Lazzoi; A, Scardino; S, Scorrano; G, Mele. (2011). Molecularly Imprinted Polymers/ Present and Future Perspective. Int. J. Mol. Sci. 12, 5908-5945. |
| [08] | Carlos. (2013). On-farm biopurification systems/ role of white rot fungi in depuration of pesticide-containing wastewaters. FEMS Microbial Lett. 345, 1-12. |
| [09] | Y, Bow; Hairul, I; Hajar, Int, J. (2015). Preparation of molecularly imprinted polymers simazine as a material potentiometric sensor. on Adv. Sci, Eng. and Information Tech. 5, 422-425. |
| [10] | M. J. Whitcome; N. Kirsch and I. A. Nicholls. (2014). Molecular imprinting science and technology: a survey of the literature for the years 2004-2011. J. Mol Recognit. 27, 297- 401. |
| [11] | Geovane, BR; Sérgio, LOM; Maria, Angélica; O, Renato; Z, Valderi; Luiz, D; et al. (2015). Imazethapyr and imazapic, bispyribac-sodium and penoxsulam/ Zooplankton and dissipation in subtropical rice paddy water. Sci Total Environ. 514, 68-76. |
| [12] | Health Canada Pest Management Regulatory Agency Registration Decision Bispyribac-sodium, (2008). |
| [13] | Hongchun Wang; WenbiaoShen; YuanlaiLou. (2019). Increasing tolerance to bispyribac-sodium is able to allow glutathione homeostasis to recover in indica rice compared with japonica rice. Pesticide Biochemistry and Physiology. 153, 28-35. |
| [14] | Wen-Tien Tsai. (2019). Trends in the Use of Glyphosate Herbicide and Its Relevant Regulations in Taiwan: A Water Contaminant of Increasing Concern. Toxics. 7 (1), 4. |
| [15] | Van Bruggen; A. H. C; He M. M; Shin K; Mai V; Jeong K. C; Finckh M. R; Morris J. G. Jr. (2018). Environmental and health effects of the herbicide glyphosate. Science of The Total Environment. 616- 617, 255-268. |
| [16] | Kolpin, DW; Thurman, EM; Lee, EA; Meyer, MT; Furlong, ET; Glassmeyer, ST. (2006). Urban contributions of glyphosate and its degradate AMPA to streams in the United States. Sci Total Environ. 354, 191-197. |
| [17] | Vinicius Marca; Sérgio de Oliveira Procópio; Alessandro Guerra da Silva; Marcelo Volf. (2015). Chemical control of glyphosate-resistant volunteer maize. Revista Brasileira de Herbicidas. 14, 103-110. |
| [18] | A. Krklješ. (2011). Radiolytic synthesis of nanocomposites based on noble metal nanoparticles and natural polymer, and their application as biomaterial. Radiation curing of composites for enhancing the features and utility in health care and industry. 128. |
| [19] | H, Kamal; E, A, Hegazy; A, B, Mostafa; A, A. (2006). Radiation synthesis and characterization of poly(N-vinyl-2-pyrrolidone/acrylic acid) and poly(N-vinyl-2-pyrrolidone/acrylamide) hydrogels for some metal-ion separation. Maksoud. J. Appl. Polym. Sci. 106, 2642-2652. |
| [20] | Samia, El-Signy; Sahar K, Mohamed; Manal F, Abou Taleb. (2014). Radiation synthesis and characterization of styrene/acrylic acid/organophilic montmorillonite hybrid nanocomposite for sorption of dyes from aqueous solutions. Polymer composite. 35, 2353-2364. |
| [21] | Rusdianasari, Y; Bow, A; Taqwa. (2014). Treatment of Coal Stockpile Wastewater by Electrocoagulation using Aluminum Electrodes. Adv. Material Research. 896, 145-148. |
| [22] | I, Kubo; R, Shoji; R, Fuchiwaki; Y, Suzuki. (2008). Atrazine Sensing Chip Based on Molecularly Imprinted Polymer Layer. Electrochemistry. 76, 541- 544. |
| [23] | Cunliffe, D; A. Kirby; C, Alexander. (2005). Molecularly imprinted drug delivery systems. Adv. Drug Delivery Rev. 57, 1836. |
| [24] | Teow, Yan, Koh; Kekhusroo, Rustomji, Bharucha. (1996). Stable Orally Active heparnoed Complexes, Continuation in part of the application. U. S. patent. |
| [25] | R, M, Silberstein; F, X, Webster; D, J, Kiemle. (2006). Spectrometric Identification of Organic Compound. John Willey & Sons. Inc. |
| [26] | Mozhgan, Hayasi; Mohammad, Karimi. (2016). Synthesis of poly(styrene-co-methacrylic acid)-coated magnetite nanoparticles as effective adsorbents for the removal of crystal violet and Rhodamine B/ a comparative study. Polym. Bull. 74, 1995–2016. |
| [27] | B, Stuarts. (2005). Infrared Spectroscopy/ Fundamental and Application. John Willey & Sons. Inc. |
| [28] | R, Liang; R, Zhang; W, Qin. (2009). Potentiometric sensor based on molecularly imprinted polymer for determination of melamine in milk. Sensor and Actuators B. 141, 544-550. |
| [29] | A, Mujahid; F; L, Peter; L. (2010). Chemical Sensors Based on Molecularly Imprinted Sol-Gel Materials. Materials. 3, 2196- 2217. |
