Vol.4 , No. 4, Publication Date: Aug. 31, 2017, Page: 26-29
[1] | Jiri Krupka, Department of Organic Technology, Faculty of Chemical Technology, University of Chemistry and Technology, Prague, Czech Republic, European Union. |
Hydrogenations are accelerated by catalysts based on some transition metals. In industrial-scale use, the heterogeneous catalysts are preferred. Although hydrogenation is affected by a number of factors, the fundamental way how to influence the course of the catalytic hydrogenation still consists in selecting a suitable active metal. Pd, Pt, Ni, Cu, Ru, Co and Rh are the most used for hydrogenation of organic substrates. In this brief review, differences in the specific catalytic properties of the above-mentioned metals are summarized and possible causes of these differences are discussed.
Keywords
Hydrogenation, Heterogeneous Catalysis, Metal Catalysts, Catalytic Properties, Molecular Modelling
Reference
[01] | D. Sanfilippo, P. N. Rylander.: Hydrogenation and Dehydrogenation, DOI: 10.1002/14356007.a13_487. pub2 (2009) in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag 2002. |
[02] | L. Cerveny et al.: Fundamental processes of industrial organic synthesis. University textbook, UCT Prague 1995. |
[03] | M. Freifelder: Practical Catalytic Hydrogenation, Wiley-Interscience, New York 1971. |
[04] | S. Nishimura: Handbook of heterogeneous catalytic hydrogenation for organic synthesis, John Wiley & Sons, New York 2001. |
[05] | J. Volf, J. Pasek: Stud. Surf. Sci. Catal. 27, 105 (1986). |
[06] | J. Krupka, J. Pasek: Curr. Org. Chem., 16, 988 (2012). |
[07] | P. Kacer, L. Cerveny: Appl. Catal. A, 229, 193 (2002) and refs. therein. |
[08] | G. C. Bond, Catalysis by Metals, Academic Press, London-New York, 1962. |
[09] | M. Boudart, G. Ertl (Ed.), H. Knözinger (Ed.), J. Weitkamp (Ed.), Handbook of Heterogeneous Catalysis, VCH Verlagsgesellschaft mbH, Weinheim, 1997. |
[10] | J. M. Thomas, W. J. Thomas, Introduction to the Principles of Heterogeneous Catalysis, Academic Press, London-New York, 1967. |
[11] | T. Bligaard, J. K. Nørskov: Heterogeneous Catalysis (Chap. 4) in A. Nilsson (Ed.): Chemical Bonding at Surfaces and Interfaces, Elsevier, Amsterdam, 2008. |
[12] | B. Hammer, J. K. Norskov: Adv. Catal. 45 (2000) 71. |
[13] | J. Greeley, J. K. Norskov, M. Mavrikakis: Ann. Rev. Phys. Chem. 53 (2002) 319. |
[14] | R. A. van Santen, M. Neurock: Molecular Heterogeneous Catalysis, Wiley-VCH, Weinheim (2006). |
[15] | G. A. Somorjai: Introduction to Surface Chemistry and Catalysis, Wiley, New York (1994). |
[16] | I. Chorkendorff, J. W. Niemantsverdriet: Concepts of Modern Catalysis and Kinetics, Wiley-VCH, Weinheim (2003). |
[17] | J. M. Thomas, W. J. Thomas: Principle and Practice of Heterogeneous Catalysis, Wiley-VCH, Weinheim (1997). |
[18] | P. Sabatier: Catalysis in Organic Chemistry, van Nostrand, New York, 1925. |
[19] | A. A. Balandin: Adv. Catal. Rel. Subj., 19, 1 (1969). |
[20] | O. Beek: Disc. Faraday Soc. 8, 118 (1950). |
[21] | T. W. Swaddle: Inorganic Chemistry, Academic Press, San Diego 1997. |
[22] | Heterogeneous Catalysis, University of Waterlooth ed. [online]; available from: http://www.science.uwaterloo.ca/~cchieh/cact/applychem/heterocat.html |
[23] | M. G. White: Heterogeneous catalysis; Prentice Hall, New Jersey, USA 1990. |
[24] | B. Coq, F. Figueras: Coordin. Chem. Rev. 178, 1753 (1998). |
[25] | V. Ponec: Adv. Catal. 32, 149 (1983). |
[26] | Yagasaki E., Masel R. I.: Surface Sci., 225, 51 (1990). |
[27] | R. I. Masel: Principles of Adsorption and Reaction on Solid Surfaces, Wiley, New York 1996. |
[28] | L. Cerveny, V. Ruzicka: Catal. Rev.– Sci. Eng., 24, 503 (1982) and refs. therein. |
[29] | L. Cerveny, V. Ruzicka: Adv. Catal., 30, 335 (1981) and refs. therein. |
[30] | L. Cerveny: Chem. Eng. Comm. 83, 31 (1989) and refs. therein. |
[31] | L. J. Broadbelt, R. Q. Snurr: Appl. Catal. A, 200, 23 (2000). |
[32] | M. Saeys, M. F. Reyniers, M. Neurock, G. B. Marin: J. Phys. Chem. B 107, 3844 (2003). |
[33] | M. Brengle, J. Bauer: J. Am. Chem. Soc. 120, 1556 (1998). |
[34] | V. Pallassana, M. Neurock, G. W. Coulston: J. Phys. Chem. B 103, 8973 (1999). |
[35] | R. A. Santen, M. Neurock: Molecular Modeling of Heterogeneous Catalytic Reactivity, DOI: 10.1002/0471227617.eoc150, in Encyclopedia of Catalysis, John Wiley and Sons (2002). |