ISSN: 2375-3846
American Journal of Science and Technology  
Manuscript Information
 
 
Profiling Heavy Metal Distribution and Contamination in Soil of Old Power Generation Station in Lagos, Nigeria
American Journal of Science and Technology
Vol.1 , No. 1, Publication Date: Jul. 7, 2014, Page: 1-10
2561 Views Since July 7, 2014, 1506 Downloads Since Apr. 14, 2015
 
 
Authors
 
[1]    

Adebola A. Adeyi , Department of Chemistry, University of Ibadan, Ibadan, Nigeria.

[2]    

Nelson Torto , Chemistry Department, Rhodes University, Grahamstown, South Africa.

 
Abstract
 

The extent of heavy metal contamination of soil of the old power generation station in Lagos was assessed. The concentrations of heavy metals in the soil samples collected were analyzed using ICP-OES after acid digestion. Principal component and correlation coefficient were used to identify the possible sources of pollution. There was a great variation in the concentrations of the metals in both surface and subsurface soil. The order of heavy metal concentrations in the surface soil was: Fe>Zn>Pb>Mn>Cu>Cr>Cd>Ni>Co while Zn, Cd, and Cu were not detected at most depths. Obvious accumulation of some of these metals was indicated in the surface soil. Soil contamination was assessed on the basis of enrichment factor (EF), contamination factor (CF) and degree of contamination. Thus, a potential pollution risk may exist, which might contribute to heavy metal loading of the Lagos Lagoon.


Keywords
 

Soil Pollution, Degree of Contamination, Enrichment Factor, Principal Component Analysis, Heavy Metal


Reference
 
[01]    

Adriano, D.C., 2001. Trace elements in terrestrial environments: biogeochemistry, bioavailability and risks of metals. Springer-Verlag, New York.

[02]    

Al Rmalli, S.W., Harrington, C.F., Ayub, M., Haris, P.I., 2005. A biomaterial based approach for arsenic removal from water. J. Environ. Monit. 7, 279–282.

[03]    

Astel, A., Astel, K., Biziuk, M., 2008. PCA and multidimensional visualization techniques united to aid in the bioindication of elements from transplanted sphagnum palustre moss exposed in the Gdan´ SK city area. Environ. Sci. Pollut. Res. 15, 41–50

[04]    

Autier, V., White, D., 2004. Examination of cadmium sorption characteristics for a boreal soil near Fairbank, Alaska. J. Hazard. Mater. 106B, 149-155.

[05]    

Bergkvist, B., Folkeson, L., Berggren, D., 1989. Fluxes of Cu, Zn, Pb, Cd, Cr, and Ni in temperate forest ecosystems. Water Air Soil Pollut. 47, 217-286.

[06]    

Bilos, C., Colomobo, J.C., Skorupka, C.N., Rodriguez Presa, M.J., 2001. Source, distribution and variability of airborne trace metals in La Plata city area, Argentina. Environ. Pollut. 111, 149–158

[07]    

Bowen, H.J.M., 1979. Environmental Chemistry of the Elements. Academic Press, London

[08]    

Buat-Menard, P., Chesselet, R., 1979. Variable influence of the atmospheric flux on the trace metal chemistry of oceanic suspended matter. Earth Planet Sci. Lett. 42, 398– 411.

[09]    

Chen, K., Jiao, J.J., Huang, J., Huang, R., 2007. Multivariate statistical evaluation of trace elements in groundwater in a coastal area in Shenzhen, China. Environ. Pollut. 147, 771–780.

[10]    

Dang Z., Liu, C., Haigh, M.J., 2002. Mobility of Heavy Metals Associated with the Natural Weathering of Coal Mine Soils. Environ. Pollut. 118, 419-426.

[11]    

Davidson, C.M., Urquhart, G.J., Ajmone-Marsan, F., Biasioli, M., da Costa Duarte, A., Dıaz-Barrientos, E., Grcman, H., Hossack, L., Hursthouse, A.S., Madrid, L., Rodrigues, S., Zupan, M., 2006. Fractionation of potentially toxic elements in urban soils from five European cities by means of a harmonized sequential extraction procedure. Anal. Chim. Acta 565, 63–72.

[12]    

Duker, A.A., Carranza, E.J.M., Hale, M., 2005. Arsenic geochemistry and health, Environ. Int. 31, 631–641.

[13]    

Elinder, C.G., 1992. Cadmium as an environmental hazard. IARC Sci. Publ. 118, 123-132.

[14]    

EPA, 1980. Exposure and risk assessment for zinc. Washington D.C. US Environmental Protection Agency. EPA 440481016

[15]    

Facchinelli, A., Sacchi, E., Mallen, L., 2001. Multivariate statistical and GIS-based approach to identify heavy metal sources in soils. Environ. Pollut. 114, 313–324.

[16]    

Feng, H., Han, X., Zhang, W., Yu, L., 2004. A preliminary study of heavy metal contamination in Yangtze River intertidal zone due to urbanization. Mar. Pollut. Bull. 49, 910–915.

[17]    

Gao, X., Chen, S., Long, A., 2008. Chemical speciation of 12 metals in surface sediments from the northern South China Sea under natural grain size. Mar. Pollut. Bull. 56, 770–797.

[18]    

González-Pérez, J.A., de Andrés, J.R., Clemente, L., Martín, J.A., González-Vila, F.J., 2008. Organic carbon and environmental quality of riverine and off-shore sediments from the Gulf of Cádiz, Spain. Environ. Chem. Lett. 6, 41–46.

[19]    

Gowd, S.S., Reddy, M.R., Govila, P.K., 2010. Assessment of heavy metal contamination in soils at Jajmau (Kanpur) and Unnao industrial areas of the Ganga Plain, Uttar Pradesh, India. J. Hazard. Mater. 174, 113-121.

[20]    

Hakanson L., 1980. An ecological risk index for aquatic pollution control: A sedimentological approach. Water. Res. 14, 975– 1001.

[21]    

Han, Y.M., Du, P.X., Cao, J.J., Posmentier, E.S., 2006. Multivariate analysis of heavy metal contamination in urban dusts of Xi’an, Central China. Sci. Total Environ. 355, 176–186.

[22]    

HMSO, 1996. Sustainable Use of Soil. Royal Commission on Environmental Pollution, London.

[23]    

Jones, H.A, and Hockey, R.D. (1964). The Geology of part of Southwestern Nigeria. Published by the Authority of the Federal Government of Nigeria, pp. 146.

[24]    

Kabata-Pendias, A., Pendias, H., 2001. Trace elements in soils and plants. 3rd edition, CRC Press, Boca Raton, Florida.

[25]    

Kabata-Pendias, A., 2004. Soil–plant Transfer of Heavy Metals – An Environmental Issue. Geoderma 122, 143–149.

[26]    

Kirkham, M.B., 2006. Cadmium in plants on polluted soils: effects of soil factors, hyperaccumulation, and amendments. Geoderma 137:19-32.

[27]    

Krishna, A.K., Govil, P.K., 2007. Soil Contamination due to Heavy Metals from an Industrial Area of Surat, Gujarat, Western India. Environ. Monit. Assess. 124, 263-275.

[28]    

Kumar, M.P., Reddy, T.M., Nithila, P., Reddy, S.J., 2005. Distribution of Toxic Trace Metals Zn, Cd, Pb, and Cu in Tirupati Soils, India. Soil Sediment Contam. 14, 471–478.

[29]    

Liu, W.H., Zhao, J.Z., Ouyang, Z.Y., Solderland, L., Liu, G.H., 2005. Impacts of Sewage Irrigation on Heavy Metal Distribution and Contamination in Beijing, China. Environ. Int. 31, 805-812.

[30]    

Lu, X., Wang, L., Li, L.Y., Lei, K., Huang, L., Kang, D., 2010. Multivariate statistical analysis of heavy metals in street dust of Baoji, NW China. J. Hazard. Mater. 173, 744-749.

[31]    

Luo, W., Wang, T., Lu, Y., Giesy, J., Shi, Y., Zheng, Y., Xing, Y., Wu, G., 2007. Landscape ecology of the Guanting Reservoir, Beijing, China: multivariate and geostatistical analyses of metals in soils. Environ. Pollut. 146, 567–576.

[32]    

McBride, M.B., 1994. Environmental chemistry of soils. 1st Edition; Oxford University Press, New York.

[33]    

Nriagu, J.O., 1988. A silent epidemic of environmental metal poisoning? Environ. Pollut. 50, 139–161.

[34]    

Obiajunwa, E.I., Pelemo, D.A., Owolabi, S.A., Fasai, M.K., Johnson-Fatokun, F.O., 2002. Characterization of Heavy Metal Pollutants of Soils and Sediments around a Crude- Oil Production Terminal using EDXRF. Nucl. Instrum. Methods Phys B 194, 61–64.

[35]    

Paterson, E., Towers, W., Bacon, J.R., Jones, M., 2003. Background levels of contaminants in Scottish soils. The Macaulay Institute, Craigiebuckler, Aberdeen.

[36]    

Pierce, F.J., Dowdy, R.H., Grigel, D.F., 1982. Concentrations of six trace metals in some major Minnesota soil series. J. Environ. Qual. 11, 416-422.

[37]    

Quevauviller, P., Lavigne, R., Cortez, L., 1989. Impact of Industrial and mine drainage wastes on the heavy metal distribution in the drainage basin and estuary of the Sado River (Portugal). Environ. Pollut. 59, 267– 86.

[38]    

Robson, M., 2003. Methodologies for assessing exposures to metals: human host factors. Ecotoxicol. Environ. Saf. 56, 104-109.

[39]    

Romic, M., Romic, D., 2003. Heavy metal distribution in agricultural top soils in urban area. Environ. Geol. 43, 795–805.

[40]    

Schiff, K.C., Weisberg, S.B., 1999. Iron as a reference elements for determining trace metal enrichment in Southern California coastal shelf sediments. Mar. Environ. Res. 48, 161– 76.

[41]    

Shakery, A., Moor, F., Razikordmahalleh, L., 2010. 19th World Congress of Soil Science, Soil Solutions for a Changing World. Brisbane, Australia.

[42]    

Shevchenko, V., Lisitzin, A., Vinogradova, A., Stein, R., 2003. Heavy metals in aerosols over the seas of the Russian Arctic. Sci. Total Environ. 306, 11-25.

[43]    

Sollito, D., Romic, M., Castrignano, A., Romic, D., Bakic, H., 2009. Assessing heavy metal contamination in soils of the Zagreb region (North Croatia) using multivariate geostatistics. Catena, doi:10.1016/j.catena.2009.11.005.

[44]    

Sutherland, R.A., 2000. Bed sediment-associated trace metals in an urban stream, Oahu, Hawaii. Environ. Geol. 39, 611– 27.

[45]    

Tahri, M., Benyaich, F., Bounakhla, M., Bilal, E., Gruffat, J.J., Moutte, J., Garcia, D., 2005. Multivariate analysis of heavy metal contents in soils. Sediments and water in the region of Meknes (central Morocco), Environ. Monit. Assess. 102, 405–417.

[46]    

Tyler, L.D., McBride, M.B., 1982. Mobility and extractability of cadmium, copper, nickel and zinc in organic and mineral soil columns. Soil Sci. 134:198-204.

[47]    

Wade, T.L., Sweet, S.T., Klein, A.G., 2008. Assessment of sediment contamination in Casco Bay, Maine, USA. Environ. Pollut. 152, 505-521.

[48]    

Walcek, C., Santis, S.D., Gentile, T., 2003, Preparation of mercury emissions inventory for eastern North America, Environ. Pollut. 123, 375–381.

[49]    

Wong, C.S.C., Li, X.D., 2004. Pb contamination and isotopic composition of urban soils in Hong Kong. Sci. Total Environ. 319,185–195.

[50]    

Zheng, N., Wang, Q.C., Liang, Z.Z., Zheng, D.M., 2008. Characterization of heavy metal concentrations in the sediments of three freshwater rivers in Huludao City, Northeast China. Environ. Pollut. 154, 135–142.





 
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