ISSN: 2375-3846
American Journal of Science and Technology  
Manuscript Information
 
 
Non Isothermal Solvation Parameters for Saturated Adipic Acid in Mixed Methanol –Water Solvents
American Journal of Science and Technology
Vol.2 , No. 2, Publication Date: Feb. 13, 2015, Page: 49-54
1864 Views Since February 13, 2015, 1003 Downloads Since Apr. 12, 2015
 
 
Authors
 
[1]    

Esam A. Gomaa, Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt.

[2]    

Elsayed M. Abou Ellef, Basic Science Department, Delta Higher Institute for Engineering & Technology, Dakhlia, Mansoura, Egypt.

[3]    

Amr A. Ibrahim, Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt.

[4]    

Amany T. Arafa, Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt.

 
Abstract
 

The molal solubilities for saturated adipic acid solutions were determined at different temperatures 298.15, 303.15, 308.15 and 313.15K in mixed methanol-water (MeOH-H2O) solvents. Different thermodynamic parameters were evaluated for the adipic acid like Gibbs free energies, enthalpies and entropies of solvation. From the experimental solubility, pH and density data, the different free energies, dissociation constants, association constants and other solvation parameters were estimated. The results were discussed.


Keywords
 

Adipic Acid, Molal Solubility, Solubility Products, Association, Dissociation, Free Energies of Solvation


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