The present paper reports the study of binary mixture N-Methyl Pyrrolidone(NMPy) – Water Solventsand their properties over the entire range of composition at 298.15K.The densities and dielectric constants for mixed NMPy – water solvents at 298.15K were accurately measured using densimeter DMA-58 and decameter DK-300 respectively. Different volumes (molar volume VM, Van der Waals volume VW, electrostriction volume Ve and crystal volume VC ) for mixed NMPy – H2O solvents were evaluated from density measurements .The results are discussed in the light of intermolecular interactions occurring in the binary mixture.
Densities, Dielectric Constant, Molar Volume, Van der Waals Volume, Electrostriction Volume, Crystal Volume, (NMPy) – Water Mixtures
[1]
A. F. Hollemanm, E. Wiberg, Inorganic Chemistry. San Diego:Academic Press. ISBN 0-12-352651-5, (2001).
[2]
David A. Wright and Pamela Welbourn, Environmenaltoxicology, Cambridge University Press, UK (2002).
[3]
Lide, R.David., ed. (2006). CRC Handbook of Chemistry andPhysics (87th ed.). Boca Raton, FL: CRC Press. ISBN 0-8493-0487-3.
[4]
Esam A.Gomaa ,Elsayed M.Abou Elleef , Amr A.Ibrahim,Amany T.Arafa, American Journal of Science and Technology,2(2015)49-54.
[5]
A. A. El-Khouly, E. A. Gomaa, and S. Abou-El-Leef, Bull. Electrochem 19, 153 (2003).
[6]
Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann.ISBN0080379419.
[7]
S.Udavari (Ed.), The Merck Index: An Encyclopedia of Chemicals, Drugs and Biologicals, 12th ed.,MerckCo.Inc.,Whitehouse Station, NJ, 1996.
[8]
Esam A.Gomaa. Eur. Chem. Bull., 1(2013 ) 259-261.J.I.Kim,Z.Phys.Chem.,N.Folge,113(1978)129.
[9]
Esam A.Gomaa, Elsayed Abou Elleef and E.A.Mahmoud, Eur. Chem. Bull, 2(2013),732-735.
[10]
Esam A Gomaa and Elsayed M.Abou Elleef, American Chemical Science Journal, 3(2013), 489-499.
[11]
Esam A. Gomaa, Elsayed M.Abou Elleef , Science and Technology, 3(2013)118-122.
[12]
Esam A Gomaa and M.G.Abdel Razek, International Research Journal of Pure and Applied Chemistry,3(2013)320-329.
[13]
Esam A.Gomaa , International Journal of Theoretical and Mathematical Physcics,3(2013)151-154.
[14]
Esam A.Gomaa and B.A.Al Jahadali, Education., 2(3),(2012)37-40.
[15]
Esam A Gomaa , American Journal of Biochemistry, 2(3), 92012),25-28.
[16]
Esam A. Gomaa , Food and Public Health, 2(3),2012, 65-68.
[17]
Esam A.Gomaa , Global Advanced Research Journal of Chemistry and Material Science, 1(2012) 35-38.
[18]
Esam A.Gomaa , Frontiers in Science, 2(2012)24-27.
[19]
Esam A Gomaa, Elsayed M.Abou Elleef, E.T.Helmy and Sh.M. Defrawy, Southern Journal of Chemistry, 21 (2013) 1-10.
[20]
Esam A Gomaa,Elsayed M.Abou Elleef,Elsayed T. Helmy, Research and reviews Journal of Chemistry, 3 (2014) 22-27.
[21]
Esam A. Gomaa ,Science and Technology,3 (2013) 123-126.
[22]
E.A.Gomaa , Research and Reviews:Journal of Chemistry, 62 (1989) 4753(2014),28-37.
[23]
Esam A.Gomaa ,Thermochimica Acta,142 (1989) 19.
[24]
Esam A. Gomaa ,Croatica Chimica Acta,. 62 (1989) 475
[25]
J.I. Kim, A. Cecal , H.J. Born, and E.A. Gomaa, Z. Physik Chemic, Neue Folge 110, 209 (1978).
[26]
J.I.Kim and E.A.Gomaa , Bull.Soci.Chim.Belg., 90(1981)391.
[27]
Esam A.Gomaa,Thermochimica Acta ,140( 1989)7.
[28]
Esam A.Gomaa, Bull.Soc.Chim.Fr. 5 (1989) 620.
